Amino Acids Functionalized Heterogeneous Chiral Catalyst: Research Monograph - Lim Kheng Wei - Książki - LAP LAMBERT Academic Publishing - 9783845407586 - 4 lipca 2011
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Amino Acids Functionalized Heterogeneous Chiral Catalyst: Research Monograph

Lim Kheng Wei

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Amino Acids Functionalized Heterogeneous Chiral Catalyst: Research Monograph

Heterogeneous asymmetric catalysis remains as an exciting research field in chiral catalysis since the heterogeneous catalyst can be separated easily from the reaction mixture compare to conventional homogeneous catalyst. The aim of the research is to develop and investigate a novel heterogeneous asymmetric catalyst using amino acid as chiral promoter. The catalysts were synthesized by attachment of amino acids such as L-glutamic acid, L-leucine and L-phenylalanine onto the hydrophilic part of hydrolyzed octadecyltrichlorosilane (OTS). The amino acidhydrolyzed OTS materials were used as catalysts for the asymmetric hydration of epoxycyclohexene to yield two diastereoisomers, namely (1R,2R)-trans-1,2-cyclohexanediol, (1S,2S)-trans-1,2-cyclohexanediol and cis-1,2-cyclohexanediol.

Media Książki     Paperback Book   (Książka z miękką okładką i klejonym grzbietem)
Wydane 4 lipca 2011
ISBN13 9783845407586
Wydawcy LAP LAMBERT Academic Publishing
Strony 96
Wymiary 150 × 6 × 226 mm   ·   149 g
Język English